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A high yield, one-pot dialysis-based process for self-assembly of near infrared absorbing gold nanoparticles
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2015-05-25 00:00 379閱讀次數(shù)
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A high yield, one-pot dialysis-based process for self-assembly of near infrared absorbing gold nanoparticles
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A high yield, one-pot dialysis-based process for self-assembly of near infrared absorbing gold nanoparticles
- A high yield, one-pot dialysis-based process for self-assembly of near infrared absorbing gold nanoparticles[詳細]
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2015-05-25 00:00
實驗操作
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A high yield, one-pot dialysis-based process for self-assembly of near infrared absorbing gold nanop
- Hypothesis:Afacile,dialysis-basedsynthesisofstablenearinfrared(nIR)absorbingplasmonicgoldnanoparticles(kmax=6501000nm)willincreasetheyieldofnIRparticlesandreducetheamountofgoldcolloidcontaminantintheproductmixture.Experiments:Chloroauricacidandsodiumthiosulfatewerereactedusingadialysismembraneasareactionvessel.Productyieldandcompositionwasdeterminedandcomparedtotraditionalsynthesismethods.Theproductparticledistribution,yield,andpartitioningofgoldbetweendispersedproductandmembrane-adsorbedgoldweredetermined.Findings:Thesynthesisresultsinpolydisperseparticlesuspensionscomprisedof70%spheroid-likeparticles,27%triangularplates,and3%rod-likestructureswitha3%batch-to-batchvariationandaprominentnIRabsorptionbandwithkmax=6501000nm.Theamountofsmallgoldcolloid(kmax=530nm;d<10nm)intheisolatedproductwasreducedby96%comparedtotraditionalmethods.Additionally,91.1%ofthegoldstartingmaterialisretainedinthesolution-basednanoparticlemixturewhile8.2%isfoundonthedialysismembrane.Thesynthesisresultsinaqualityratio(QR=AbsnIR/Abs530)of1.72.4(twicethatofprevioustechniques)and14.3timesgreaterODmlyieldofthenIR-absorbingnanoparticlefraction.[詳細]
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2018-08-31 10:11
產(chǎn)品樣冊
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Gold Nanoparticles 納米金市場報價表
- 產(chǎn)品介紹:納米金(GoldNanoparticles)的制備方法主要采用還原劑,如檸檬酸鈉,硼氫化鈉等還原氯金酸HAuCl44H2O。氯金酸HAuCl44H2O在還原劑的作用下,可以聚合成一定大小的金納米顆粒,形成帶負電的疏水膠溶液。由于靜電作用而成為穩(wěn)定的膠體狀態(tài),故稱膠體金(Colloidalgold)。納米金分散在水中:GoldNanoparticlesdispersedinwater粒徑:5nm-100nm濃度:0.05,0.1mg/ml包裝:25ml/50ml/更大粒徑濃度價格(元/規(guī)格)5nm0.05mg/ml1000元/25ml1600元/50ml0.1mg/ml2000元/25ml3300元/50ml10nm0.05mg/ml1000元/25ml1600元/50ml0.1mg/ml2000元/25ml3300元/50ml20nm0.05mg/ml1000元/25ml1600元/50ml0.1mg/ml2000元/25ml3300元/50ml30nm0.05mg/ml1000元/25ml1600元/50ml0.1mg/ml2000元/25ml3300元/50ml40nm0.05mg/ml1000元/25ml1600元/50ml0.1mg/ml2000元/25ml3300元/50ml50nm0.05mg/ml1000元/25ml1600元/50ml0.1mg/ml2000元/25ml3300元/50ml60nm0.05mg/ml1000元/25ml1600元/50ml0.1mg/ml2000元/25ml3300元/50ml70nm0.05mg/ml1000元/25ml1600元/50ml0.1mg/ml2000元/25ml3300元/50ml80nm0.05mg/ml1000元/25ml1600元/50ml0.1mg/ml2000元/25ml3300元/50ml90nm0.05mg/ml1000元/25ml1600元/50ml0.1mg/ml2000元/25ml3300元/50ml100nm0.05mg/ml1000元/25ml1600元/50ml0.1mg/ml2000元/25ml3300元/50ml葡萄糖修飾納米金分散在水中:GlucoseofmodifiedGoldNanoparticlesdispersedinwater粒徑:5nm-100nm濃度:0.05,0.1mg/ml包裝:25ml/50ml/更大粒徑濃度價格(元/規(guī)格)5nm0.05mg/ml2800元/25ml3800元/50ml0.1mg/ml3950元/25ml5250元/50ml10nm0.05mg/ml2800元/25ml3800元/50ml0.1mg/ml3950元/25ml5250元/50ml20nm0.05mg/ml2800元/25ml3800元/50ml0.1mg/ml3950元/25ml5250元/50ml30nm0.05mg/ml2800元/25ml3800元/50ml0.1mg/ml3950元/25ml5250元/50ml40nm0.05mg/ml2800元/25ml3800元/50ml0.1mg/ml3950元/25ml5250元/50ml50nm0.05mg/ml2800元/25ml3800元/50ml0.1mg/ml3950元/25ml5250元/50ml60nm0.05mg/ml2800元/25ml3800元/50ml0.1mg/ml3950元/25ml5250元/50ml70nm0.05mg/ml2800元/25ml3800元/50ml0.1mg/ml3950元/25ml5250元/50ml80nm0.05mg/ml2800元/25ml3800元/50ml0.1mg/ml3950元/25ml5250元/50ml90nm0.05mg/ml2800元/25ml3800元/50ml0.1mg/ml3950元/25ml5250元/50ml100nm0.05mg/ml2800元/25ml3800元/50ml0.1mg/ml3950元/25ml5250元/50mlPVP,聚苯乙烯修飾納米金分散在水中:PVP,polystyreneofmodifiedGoldNanoparticlesdispersedinwater粒徑:5nm-100nm濃度:0.05,0.1mg/ml包裝:25ml/50ml/更大粒徑濃度價格(元/規(guī)格)5nm0.05mg/ml1800元/25ml2500元/50ml0.1mg/ml2650元/25ml4250元/50ml10nm0.05mg/ml1800元/25ml2500元/50ml0.1mg/ml2650元/25ml4250元/50ml20nm0.05mg/ml1800元/25ml2500元/50ml0.1mg/ml2650元/25ml4250元/50ml30nm0.05mg/ml1800元/25ml2500元/50ml0.1mg/ml2650元/25ml4250元/50ml40nm0.05mg/ml1800元/25ml2500元/50ml0.1mg/ml2650元/25ml4250元/50ml50nm0.05mg/ml1800元/25ml2500元/50ml0.1mg/ml2650元/25ml4250元/50ml60nm0.05mg/ml1800元/25ml2500元/50ml0.1mg/ml2650元/25ml4250元/50ml70nm0.05mg/ml1800元/25ml2500元/50ml0.1mg/ml2650元/25ml4250元/50ml80nm0.05mg/ml1800元/25ml2500元/50ml0.1mg/ml2650元/25ml4250元/50ml90nm0.05mg/ml1800元/25ml2500元/50ml0.1mg/ml2650元/25ml4250元/50ml100nm0.05mg/ml1800元/25ml2500元/50ml0.1mg/ml2650元/25ml4250元/50ml功能化的納米金分散在水中:(氨基或羧基修飾的)GoldNanoparticlesaminefunctioninwater/GoldNanoparticlescarboxylfunctioninwater:粒徑:5nm-100nm濃度:0.05,0.1mg/ml包裝:25ml/50ml/更大粒徑濃度價格(元/規(guī)格)5nm0.05mg/ml2500元/25ml3650元/50ml0.1mg/ml3550元/25ml5250元/50ml10nm0.05mg/ml2500元/25ml3650元/50ml0.1mg/ml3550元/25ml5250元/50ml20nm0.05mg/ml2500元/25ml3650元/50ml0.1mg/ml3550元/25ml5250元/50ml30nm0.05mg/ml2500元/25ml3650元/50ml0.1mg/ml3550元/25ml5250元/50ml40nm0.05mg/ml2500元/25ml3650元/50ml0.1mg/ml3550元/25ml5250元/50ml50nm0.05mg/ml2500元/25ml3650元/50ml0.1mg/ml3550元/25ml5250元/50ml60nm0.05mg/ml2500元/25ml3650元/50ml0.1mg/ml3550元/25ml5250元/50ml70nm0.05mg/ml2500元/25ml3650元/50ml0.1mg/ml3550元/25ml5250元/50ml80nm0.05mg/ml2500元/25ml3650元/50ml0.1mg/ml3550元/25ml5250元/50ml90nm0.05mg/ml2500元/25ml3650元/50ml0.1mg/ml3550元/25ml5250元/50ml100nm0.05mg/ml2500元/25ml3650元/50ml0.1mg/ml3550元/25ml5250元/50ml[詳細]
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2018-10-09 10:01
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Coup領 of near infrared spectroscopy to automatic continuous online monitoring of polymerization r
- Insitunearinfrared(NIR)spectroscopyisperformedsimultaneouslywithautomaticcontinuousonlinemonitoringofpolymerizationreactions(ACOMP)duringmethylmethacrylatepolymerization.ACOMPisanabsolutetechniquethatfurnishesweightaveragemolecularmassMw,intrinsicviscosity,monomerconversion,andothercharacteristics,whereasNIRfurnishesmonomerconversiondataviaanempiricalcalibration.AnadvantageofinsituNIRisthatitfurnishesimmediateinformationontheconversioninthereactor,whereasACOMPreliesoncontinuouswithdrawalanddilutionofasmallstreamofreactorfluid,sothatthereisalagtimeofseveralminutesbetweenwhatACOMPreportsandwhatisoccurringinthereactor.SimultaneousmonomerconversiondatafrominsituNIRandACOMP,thelatterderivedfrombothrefractiveindexandUVabsorption,arecomparedandfoundtobeingoodagreement.TheevolutionofconversionkineticsandMwgenerallyconformtothepredictionsoftheQuasi-SteadyStateApproximation.Havingestablishedtheagreementbetweenthemethods,thepathisnowopenforcombiningNIRwithACOMPtocharacterizeincreasinglycomplexsystems,suchascopolymerizationwithtwoormoremonomericspecies,thatarenotfeasiblebyeithertechniqueseparately.[詳細]
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