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Aggregation Kinetics of Multiwalled Carbon Nanotubes in Aquatic Systems: Measurements and Environmen
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2018-08-31 10:11 581閱讀次數(shù)
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作者:NAVIDB.SALEH,LISAD.PFEFFERLE,ANDMENACHEMELIMELECH ?。―epartmentofChemicalEngineering,YaleUniversity,NewHaven,Connecticut06520-8286) 摘要:Theinitialaggregationkineticsofmultiwalledcarbonnanotubes(MWNTs)wereexaminedthroughtime-resolveddynamiclightscattering.AggregationofMWNTswasevaluatedbyvaryingsolutionpHandtheconcentrationofmonovalent(NaCl)anddivalent(CaCl2andMgCl2)salts.SuwanneeRiverhumicacid(SRHA)wasusedtostudytheeffectofbackgroundnaturalorganicmatteronMWNTaggregationkinetics.IncreasingsaltconcentrationandadditionofdivalentcalciumandmagnesiumionsinducedMWNTaggregationbysuppressingelectrostaticrepulsion,similartoobservationswithaquaticcolloidalparticles.Thecriticalcoagulationconcentration(CCC)valuesforMWNTswereestimatedas25mMNaCl,2.6mMCaCl2,and1.5mMMgCl2.AnincreaseinsolutionpHfromacidic(pH3)tobasic(pH11)conditionsresultedinasubstantial(over2ordersofmagnitude)decreaseinMWNTaggregationkinetics,suggestingthepresenceofionizablefunctionalgroupsontheMWNTcarbonscaffold.ThepresenceofhumicacidinsolutionmarkedlyenhancedthecolloidalstabilityofMWNTs,reducingtheaggregationratebynearly2ordersofmagnitude.TheenhancedMWNTstabilityinthepresenceofhumicacidisattributabletostericrepulsionimpartedbyadsorbedhumicacidmacromolecules.OurresultssuggestthatMWNTsarerelativelystableatsolutionpHandelectrolyteconditionstypicalofaquaticenvironments.
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Aggregation Kinetics of Multiwalled Carbon Nanotubes in Aquatic Systems: Measurements and Environmen
- 作者:NAVIDB.SALEH,LISAD.PFEFFERLE,ANDMENACHEMELIMELECH ?。―epartmentofChemicalEngineering,YaleUniversity,NewHaven,Connecticut06520-8286) 摘要:Theinitialaggregationkineticsofmultiwalledcarbonnanotubes(MWNTs)wereexaminedthroughtime-resolveddynamiclightscattering.AggregationofMWNTswasevaluatedbyvaryingsolutionpHandtheconcentrationofmonovalent(NaCl)anddivalent(CaCl2andMgCl2)salts.SuwanneeRiverhumicacid(SRHA)wasusedtostudytheeffectofbackgroundnaturalorganicmatteronMWNTaggregationkinetics.IncreasingsaltconcentrationandadditionofdivalentcalciumandmagnesiumionsinducedMWNTaggregationbysuppressingelectrostaticrepulsion,similartoobservationswithaquaticcolloidalparticles.Thecriticalcoagulationconcentration(CCC)valuesforMWNTswereestimatedas25mMNaCl,2.6mMCaCl2,and1.5mMMgCl2.AnincreaseinsolutionpHfromacidic(pH3)tobasic(pH11)conditionsresultedinasubstantial(over2ordersofmagnitude)decreaseinMWNTaggregationkinetics,suggestingthepresenceofionizablefunctionalgroupsontheMWNTcarbonscaffold.ThepresenceofhumicacidinsolutionmarkedlyenhancedthecolloidalstabilityofMWNTs,reducingtheaggregationratebynearly2ordersofmagnitude.TheenhancedMWNTstabilityinthepresenceofhumicacidisattributabletostericrepulsionimpartedbyadsorbedhumicacidmacromolecules.OurresultssuggestthatMWNTsarerelativelystableatsolutionpHandelectrolyteconditionstypicalofaquaticenvironments.[詳細(xì)]
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2018-08-31 10:11
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