Syntheses and properties of fluorinated phosphate acrylates used for UV-curing coatings The acrylated perfluoroalkyl phosphates (PFPA I and PFPA II) used as an oligomer and monomer, respectively, for UV-curing systems were synthesized... Syntheses and properties of fluorinated phosphate acrylates used for
UV-curing coatings
The acrylated perfluoroalkyl phosphates (PFPA I and PFPA II) used as an oligomer and monomer, respectively,
for UV-curing systems were synthesized and characterized with 1H NMR and FTIR spectra. The
photopolymerization behavior was investigated by using photo-DSC analysis, showing that both acrylates
were photopolymerized quickly to a moderate final unsaturation conversion at the presence of a
photoinitiator. The limiting oxygen indices of the UV-cured pure filmswere determined to be over 35. The
surface properties of UV-cured polyurethane films added PFPAs, respectively, as additives were investigated
by measuring the contact angles. The results showed that the addition of a small amount of PFPA I or
PFPA II efficiently led to the increases in the contact angles, and the decreases in the surface tension. The
X-ray photoelectron spectroscopy analysis confirmed that the film surface was enriched with fluorinated
species. 展開