摘要 目的：建立薄膜電導(dǎo)率法總有機(jī)碳分析儀測量結(jié)果不確定度的評(píng)定方法方法：分析了測量過程中不確定度的主要來源，即工作曲線的不確定度測量儀器讀數(shù)分辨率導(dǎo)致的不確定度測量不重復(fù)性引起的不確定度標(biāo)準(zhǔn)溶液引起的不確定度等，分別量化后合成標(biāo)準(zhǔn)不確定度，得到總有機(jī)碳測量的擴(kuò)展不確定度結(jié)果：通過對(duì)HTY-2500總有機(jī)碳分析儀在2000g•L-1測量點(diǎn)測量結(jié)果不確定度的評(píng)定，其擴(kuò)展不確定度為U95 = 49（g•L-1）（k=2）結(jié)論：本方法所建立的測量結(jié)果不確定度評(píng)定方法準(zhǔn)確可靠，可為薄膜-電導(dǎo)率法總有機(jī)碳分析儀的測量結(jié)果不確定度評(píng)定提供較為準(zhǔn)確簡便的方法 關(guān)鍵詞：總有機(jī)碳；測量不確定度；薄膜電導(dǎo)率法 中圖分類號(hào)：R917 文獻(xiàn)標(biāo)識(shí)碼：A 文章編號(hào)：0254-1793（2008）12-0-0 Evaluation of Measurement Uncertainty for the Total Organic Carbon Analyzer with Membrane Conductmetric Detection Technology YAN Xiang-qing1，WU Xu-mei2 (1.Zhe極ang Province Institute of Metrology, Hangzhou, 310013, China;2. Hangzhou Tailin Bioengineering Equipments Co. LTD, Hangzhou, 310052, China) Abstract: Purpose: The article set up an evaluation method of measurement uncertainty for the total organic carbon analyzer with membrane conductmetric detection technology. Method: The article analyzed the main resources of the uncertainty of the measurement, which include uncertainty of the working curve, uncertainty of the resolution ratio of the instrument, uncertainty of measure unrepeatability, uncertainty of standard solution, etc. It quantified these uncertainties respectively and composed them to a standard uncertainty. Finally it got the expanded uncertainty of the total organic carbon measurement. Result: It evaluated the measurement uncertainty of the total organic carbon analyzer at 2000g•L-1 and got the expanded uncertainty which is U95 = 49（g•L-1）（k=2）. Conclusion: The evaluation method of measurement uncertainty set up by the article is accurate, reliable, and it can offer comparatively exact and convenient method for measurement uncertainty evaluation of the total organic carbon analyzer with membrane conductmetric detection technology. Key words: total organic carbon; uncertainty of a measurement; membrane-conductometric detection technology TOC總有機(jī)碳分析儀HTY-DI1000