We report on optical waveguide structures containing a thin liquid crystal (LC) film held between two photochromic command surfaces. The command surfaces consist of three monomolecular layers of a polymer with azobenzene side chains deposited according to the Langmuir-Blodgett-Kuhn technique. When exposed to light of appropriate wavelength, the command surfaces undergo a trans-cis photoisomerization process that induces a reversible change in the liquid crystalline orientation. Such an orientation change of the LC alters the optical properties of the optical waveguide. We present experiments on the dynamics of the LC orientation process.-The transition is shown to be continuous, with the degree of orientation dependent on the ratio of the cis-trans chromophore concentration ratio in the command surface. 組合式多功能橢偏儀