全部評論(4條)
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- 丨美好丨 2015-08-17 00:00:00
- 600
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- 中醫(yī)藥杭 2015-08-17 00:00:00
- 去某寶看下
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- rnfpyy 2015-08-17 00:00:00
- 三百塊左右
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- 安凌氏 2015-08-17 00:00:00
- 300元 傳感器(英文名稱:transducer/sensor)是一種檢測裝置,能感受到被測量的信息,并能將感受到的信息,按一定規(guī)律變換成為電信號或其他所需形式的信息輸出,以滿足信息的傳輸、處理、存儲、顯示、記錄和控制等要求。 傳感器的特點包括:微型化、數(shù)字化、智能化、多功能化、系統(tǒng)化、網(wǎng)絡化。它是實現(xiàn)自動檢測和自動控制的首要環(huán)節(jié)。傳感器的存在和發(fā)展,讓物體有了觸覺、味覺和嗅覺等感官,讓物體慢慢變得活了起來。通常根據(jù)其基本感知功能分為熱敏元件、光敏元件、氣敏元件、力敏元件、磁敏元件、濕敏元件、聲敏元件、放射線敏感元件、色敏元件和味敏元件等十大類。
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- Keywords:Epoxides;Amines;2-Aminoalcohols;Yttriumnitratehexahydrate;RegioselectivityAminoalcoholsconstituteanimportantclassofcompoundshavingbothchemicalandbiologicalapplic... Keywords: Epoxides; Amines; 2-Amino alcohols; Yttrium nitrate hexahydrate; Regioselectivity Amino alcohols constitute an important class of compoundshaving both chemical and biological applications. They are important pharmacophores present in various inhibitors and are used as building blocks for the synthesis of biologically active natural products, insecticidal agents and chiral auxillaries for asymmetric reactions.1a–f They act as starting materials for the synthesis of oxazolines which are useful in the polymer industry.1g Owing to their widespread applications, the synthesis of amino alcohols has received much attention in recent years. Traditionally, 2-amino alcohols are prepared by heating an epoxide with an excess of amine at elevated temperature. The use of a high temperature leads to undesired side reactions and also limits the applicability towards temperature sensitive substrates. To overcome these drawbacks various promoters such as ZnCl2,2 ScOTf,3 MgBr2OEt2,4 67 9 bismuth salts,5 CoCl2, CuBF4, DIPAT,8 Ti(OiPr)4, 1011 12TaCl5, ZrCl4, Sm(OTf)3, potassium dodecatungstocobaltate, 13 and aluminosilicate14 have been employed for the above transformation. The use of non-conventional techniques such as microwave irradiation at elevated temperaturehas also been reported.15 Recently, the use of Al(OTf)3 (1 mol %) as catalyst in toluene at reflux has also been reported.16 Although significant advances have been made in this area, low regioselectivity, longer reaction time, use of elevated temperature, high catalyst loading, toxic solvents and lower substrate compatibilitylimit their applications.Thus there is a need to develop an efficient catalytic protocol for ring opening of various epoxides with aliphatic, aromatic andheteroaromatic amines under ambient conditions 展開
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